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Case study 04 / 12 · Division I
Division I · Case Study 04

Printing Inks

Phys–Chem (Fenton) + Thermal

Ink and wash effluents are low-volume but extremely concentrated — high COD, pigments, resins and solvents with very low biodegradability. KEMISTA breaks the emulsions chemically, oxidises refractory organics and concentrates the residue.

90%
COD removal
Reuse
Distillate
<0.2
BOD/COD handled
Selected treatment train
Ink wash → Segregation + EQ → Emulsion break → Fenton oxidation → Filter press → Evaporation → Distillate reuse
Indicative influent characteristics
Flow batch low
pH – 4–10
COD mg/L 5,000–50,000
Colour Pt-Co very high
TSS mg/L 1,000–10,000
BOD/COD – < 0.2
COD reduction along the train
COD (mg/L)
25,000
Raw
12,000
+Coag
4,000
+Fenton
800
+Evap
Why this configuration
Emulsion breaking with pH and coagulant releases bound pigment and resin.
Fenton / advanced oxidation tackles the non-biodegradable COD fraction.
Evaporation achieves high volume reduction where biology is ineffective.
Hazardous-waste compliant conditioning and routing of the concentrate.
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