Technology divisions

One oxidation-and-separation toolkit, four divisions.

The waste-liquid and spent-caustic divisions share one toolkit — precipitation, ion exchange, oxidation, membranes and evaporation — applied to industrial effluent, refinery spent caustic, then liquid radioactive effluent. The fourth division handles everything that is not waste-liquid.

I Industrial Waste-Liquid II Spent Caustic III Nuclear Waste-Liquid IV Waste Management
I
Division I
Non-radioactive

Industrial Waste-Liquid Treatment

Sector-by-sector treatment of non-radioactive effluent. Each plant is assembled from a proven toolkit and sequenced to match the effluent, the discharge consent and the client's reuse and recovery goals — for discharge compliance, water reuse and resource recovery.

Industrial waste-liquid clarifier basins
REFERENCE PFD · COAG/FLOC + DAF + BIOLOGICAL POLISHING WWT-001
RAW EFFLUENT
SRC
SCREEN + EQ
T-101
PAC · FeCl₃
polymer
COAG / FLOC
M-201/202
DAF
DAF-301
float · sludge
→ dewater
biogas
→ CHP
BIOLOGY
UASB · MBBR
MEDIA FILTER
F-401
REUSE
→ DISCHARGE
Source / feed Active treatment Water · recycle Residue Recovered value
FIRM
KEMISTA
DRAWING
Industrial WW — Coag/Floc + DAF + Biology
DWG NO.
WWT-001
REV
B

Physical–Chemical

Coagulation, flocculation, pH adjustment, DAF, clarification, filtration and ion exchange.

DAF Lamella Filter press

Biological

Aerobic AS/MBBR/MBR and high-rate anaerobic UASB/EGSB convert organic load — and recover biogas.

UASB / EGSB MBBR MBR

Membranes

Ultrafiltration and reverse osmosis separate solids and salts for reuse-grade permeate.

UF RO NF

Thermal & ZLD

Evaporation, crystallisation and brine concentration recover water and salts to near-zero discharge.

MVR evap Crystalliser Centrifuge
See 11 sector case studies
II
Division II
Refinery & petrochemical

Spent Caustic Treatment

Spent caustic is the alkaline waste from caustic scrubbing of hydrocarbon streams in refineries and ethylene/olefins plants — carrying sulfides, mercaptans, phenols and naphthenic acids at pH 12–14 and COD up to 250,000 mg/L. KEMISTA destroys these contaminants by oxidation: mild advanced oxidation (AOP) for lighter loads, high-pressure wet air oxidation (WAO) for concentrated sulfidic streams.

Wet-air-oxidation reactor vessel
→ WAO

Sulfidic

From H₂S and mercaptan scrubbing on olefins and LPG units. High sulfide (Na₂S, NaHS) and COD — the prime target for wet air oxidation.

→ AOP

Phenolic / Cresylic

From gasoline and kerosene treating. Phenolates and cresylates drive COD, colour and toxicity — well suited to advanced oxidation.

AOP + de-oil

Naphthenic

From jet and diesel treating. Naphthenic acids and emulsified hydrocarbons, treated by oxidation after de-oiling.

SECTION 1 · ADVANCED OXIDATION SC-PID-001
SPENT CAUSTIC
pH 12–14 · high COD
SRC
ACID CONDITIONING
pH 3–5 · H₂S → scrubber
T-101
OXIDATION REACTOR
H₂O₂ · Fe catalyst · •OH
R-201
NEUTRALISE + SEPARATE
caustic · spent catalyst out
V-401
TO BIOLOGY
biodegradable effluent → ETP
OUT
Mild conditions — atmospheric, 20–90 °C; low CAPEX.
Hydroxyl radicals mineralise phenolics, colour and toxicity.
Renders a refractory caustic biologically treatable.
SECTION 2 · WET AIR OXIDATION SC-PID-002
SPENT CAUSTIC
concentrated sulfidic
SRC
HP FEED PUMP
to system pressure
P-101
FEED/EFFLUENT HX
economiser · heat recovery
E-101
WAO REACTOR
air · 200–280 °C · 35–200 bar
R-201
COOL · SEPARATE · TREATED
low-odour · off-gas → oxidiser
OUT
Handles the strongest streams — COD to 250,000 mg/L.
No dilution, no combustion — minimal NOₓ / SOₓ.
Energy self-sufficient once started via heat exchange.
Route selection
Section 1 · AOP
Section 2 · WAO
Driver
Hydroxyl radicals (•OH)
Dissolved O₂ at high T/P
Temperature
20–90 °C
200–280 °C
Pressure
Atmospheric
35–200 bar
Oxidant
H₂O₂ · O₃ · O₂ + catalyst
Compressed air
Best for
Phenolic / dilute sulfidic
Concentrated sulfidic
COD range
< 50,000 mg/L
50,000–250,000 mg/L
Stainless evaporator and ion-exchange columns
III
Division III
Radioactive effluent

Nuclear Waste-Liquid Treatment

KEMISTA treats both liquid and gaseous waste effluents to remove, concentrate or isolate radioactive isotopes and hazardous chemicals before they are recycled or released — driving residual activity well below strict national and EU regulatory limits across routine operation, maintenance and decommissioning.

01

Remove

Capture radioactive ions and particulates onto resins, filters and adsorbers.

02

Concentrate

Reduce volume by evaporation and dewatering for stable conditioning.

03

Isolate

Hold short-lived isotopes for decay; immobilise residues for safe long-term storage.

LIQUID EFFLUENT TRAIN NUW-L01
COLLECTION & SEGREGATION
SRC
FILTRATION
suspended solids
F-101
PRECIPITATION
Cs · Sr · Co co-precip
M-201
ION EXCHANGE
selective resin beds
IX-301
EVAPORATION
→ concentrate · conditioning
EV-401
PURIFIED WATER
recycle / monitored discharge
OUT
Co-precipitation captures Cs, Sr and Co into settleable sludge.
Selective & chelating resin beds polish dissolved activity.
Evaporation concentrates residue; condensate polished for reuse.
GASEOUS EFFLUENT TRAIN NUW-G01
PROCESS VENTS & OFF-GAS
SRC
HEPA PRE-FILTER
particulate removal
HF-101
CHARCOAL ADSORBER
iodine capture
CA-201
DELAY & DECAY
noble-gas decay
DD-301
MONITORED STACK
continuous AIT · release within limits
OUT
HEPA filtration captures airborne radioactive particulates.
Activated-charcoal beds trap radioactive iodine.
Delay & decay tanks hold noble gases until decayed.
IV
Division IV
Both industries

Waste Management

Everything that is not waste-liquid — the solid, hazardous, gaseous and conditioned wastes arising in both industries. KEMISTA segregates, treats, conditions and routes each waste category to the right recovery or disposal pathway, with integrated routing and performance tracking across the site.

Waste management storage tanks

Solid & Hazardous

Segregation, treatment and disposal of solid and hazardous industrial and radioactive wastes.

Segregation
Volume reduction
Licensed disposal

Gaseous / Air

Off-gas and ventilation treatment — filtration, adsorption and monitored release within limits.

HEPA / charcoal
Incineration
Stack monitoring

Conditioning & Packaging

Immobilisation, conditioning and packaging of concentrates and residues for interim storage.

Immobilisation
Conditioning
Interim storage

See how the toolkit maps to your sector.

Open the interactive technology selection matrix and explore the eleven industry case studies.

Selection matrix Case studies