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Case study 09 / 12 · Division I
Division I · Case Study 09

Fertilisers

Stripping + Precipitation + Bio-N + ZLD

Fertiliser-plant effluents are dominated by ammonia, nitrate, urea, phosphate and fluoride at high TDS. KEMISTA recovers nitrogen as marketable product, precipitates struvite, removes residual nitrogen biologically and crystallises salts.

85%
Nitrogen recovery
95%
Water recovery
Yes
Salt recovery
Selected treatment train
Condensate → EQ + pH → Ammonia stripping → Struvite precip → Biological N → Evaporator / crys → Reuse
Indicative influent characteristics
pH – 4–11
NH₃-N mg/L 500–5,000
NO₃-N mg/L 200–2,000
Phosphate mg/L 50–500
Fluoride mg/L 10–200
TDS mg/L 5,000–30,000
Cumulative water recovery
recovery (%)
55%
Strip+ppt
78%
+Bio
93%
+Evap
96%
+Crys
Why this configuration
Nitrogen recovery as ammonium sulphate turns a pollutant into product.
Struvite precipitation co-recovers nitrogen and phosphorus as slow-release fertiliser.
Biological polishing removes residual nitrate to consent.
ZLD crystallisation recovers salts and approaches zero liquid discharge.
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